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Rob Van Dam is considered one of the biggest legends in the world of professional wrestling, having achieved a lot of success in this business. He has been active in the wrestling world since the early 90s, and he has worked in multiple major professional wrestling promotions like WWE and ECW.
Van Dam earned his early success while working in ECW, and he became extremely over among the fans for his high flying wrestling style. He became a part of WWE after the promotion was bought by Vince McMahon. He was a big part of the WWE vs Alliance storyline as he was one of the key members of Team Alliance.

Rob Van Dam revealed the most painful moves
He mostly received a mid card push in WWE as he won multiple mid card titles, including some tag team titles. He was promoted as a main event for the first time in 2006 when he won the Money in the Bank Ladder match at WrestleMania 22 and successfully cashed it in to win the WWE Championship at the One Night Stand event of the same year.
Rob Van Dam won the WWE Championship and ECW Championship simultaneously in 2006
Rob Van Dam had been inducted into the WWE Hall of Fame in the class of 2021. He is considered one of the most high flying wrestlers in professional wrestling history. Recently, Rob Van Dam went live on his YouTube channel, where he revealed which wrestling moves hurt the most. Here is what the former WWE Champion has to say;

Van Dam was inducted into the WWE Hall of Fame in 2006
"I will say that one of the most painful finishing moves is, and I've said this on here before, but the Alabama Slammer, one of my least favorite moves to take. Patriot used to do it to me in Japan, and Bob Holly, of course. You're up there and you're just waiting to take this back bump and hope that you don't bounce the back of your head off the mat, and there's so much momentum going with it as you can see. You know, it's not a very soft bump to take."
"I mean it's similar in the way that your body is moving kind of backwards, you know, like you're up and your feet are out and then you're going back, you could easily hit the back of your head on the mat, and often do, bounce off. Sometimes you can land flat or you could land, you know, more vertical and just land on the back of your shoulders and your head, like boom. Like so a lot of variables with that one, but I wouldn't say that it's just easy to take." Said the WWE Hall of Famer.
h/t to Wrestling Inc. for transcription.